257885

Trimethylsilylcyclopentadien, Isomermischung

• Synonym(e): NSC 176274
• Empirische Formel (Hill-System): C₈H₁₄Si
• CAS-Nummer: 3559-74-8
• Molekulargewicht: 138.28
• MDL-Nummer: MFCD00010666
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24855613
• NACRES: NA.22
• Form: liquid

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Brechungsindex: n20/D 1.471 (lit.)
• bp: 138-140 °C (lit.)
• Dichte: 0.833 g/mL at 25 °C (lit.)
• Lagertemp.: −20°C
• SMILES String: C[Si](C)(C)C1C=CC=C1
• InChI: 1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
• InChIKey: VMFHCJPMKUTMMQ-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.

Anwendung

Reactant involved in:

• Diels-Alder reactions
• Synthesis of ring-functionalized molybdenocene complexes
• Allyl isomerization
• Aromatization of C5 rings
• Synthesis of N-hydroxyindoles via nucleophilic addition

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 84.2 °F - closed cup
• Flammpunkt (°C): 29 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter