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25190

Sigma-Aldrich

4-Chlor-2-methylphenoxyessigsäure

technical, ≥95.0% (T)

Synonym(e):

4-Chlor-o-tolyloxyessigsäure, MCPA

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About This Item

Lineare Formel:
ClC6H3(CH3)OCH2CO2H
CAS-Nummer:
94-74-6
Molekulargewicht:
200.62
Beilstein:
2051752
EG-Nummer:
202-360-6
MDL-Nummer:
MFCD00004306
UNSPSC-Code:
12352100
PubChem Substanz-ID:
57648118
NACRES:
NA.22

Qualität

technical

Qualitätsniveau

100

Assay

≥95.0% (T)

Form

solid

mp (Schmelzpunkt)

114-118 °C (lit.)

Löslichkeit

water: insoluble(lit.)

Funktionelle Gruppe

carboxylic acid
chloro

SMILES String

Cc1cc(Cl)ccc1OCC(O)=O

InChI

1S/C9H9ClO3/c1-6-4-7(10)2-3-8(6)13-5-9(11)12/h2-4H,5H2,1H3,(H,11,12)

InChIKey

WHKUVVPPKQRRBV-UHFFFAOYSA-N

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Allgemeine Beschreibung

4-Chloro-2-methylphenoxyacetic acid (MPCA) is a herbicide. Various MCPA-mineralising bacterial combinations has been tested using a high-throughput microplate radiorespirometric mineralisation assay. Degradation mechanisms of OH and MCPA including molecular form and anionic form have been studied. Rapid and sensitive LC-electrospray tandem mass spectrometry method has been developed for the quantitation of MCPA in water and soil samples.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
BCCG4807
BCCG0676
BCCG0675
BCBZ7838
BCBV3948

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Urse S Krüger et al.
Pest management science, 71(2), 257-265 (2014-04-17)
The herbicide 4-chloro-2-methylphenoxyacetic acid (MCPA) is found frequently in Danish groundwater in concentrations exceeding the EU threshold limit of 0.1 µg L(-1) . Groundwater is used for drinking water, and one potential remediation strategy is bioaugmentation using inoculation of sand filters at
Xiaohua Ren et al.
Chemosphere, 88(1), 39-48 (2012-03-27)
The initial degradation mechanisms of ⁱOH and 4-chloro-2-methylphenoxyacetic acid (MCPA) including molecular form and anionic form are studied at the MPWB1K/6-311+G(3df, 2p)//MPWB1K/6-31+G(d, p) level. Possible reaction pathways of H-atom abstraction and ⁱOH addition are considered in detail. By result comparison
Erkin Gözdereliler et al.
Applied and environmental microbiology, 79(1), 367-375 (2012-11-06)
Two 4-chloro-2-methylphenoxyacetic acid (MCPA)-degrading enrichment cultures selected from an aquifer on low (0.1 mg liter(-1)) or high (25 mg liter(-1)) MCPA concentrations were compared in terms of metabolic activity, community composition, population growth, and single cell physiology. Different community compositions
G G Bond et al.
British journal of industrial medicine, 50(4), 340-348 (1993-04-01)
For the purpose of assessing the human carcinogenic potential of the chlorophenoxy herbicides MCPA, MCPP, and 2,4-DP, the relevant epidemiological and toxicological evidence is reviewed. These compounds have not produced tumours in animal studies conducted under current test guidelines, giving
Edgar Hiller et al.
Chemosphere, 87(5), 437-444 (2011-12-31)
Herbicide leaching through soil into groundwater greatly depends upon sorption-desorption and degradation phenomena. Batch adsorption, desorption and degradation experiments were performed with acidic herbicide MCPA and three soil types collected from their respective soil horizons. MCPA was found to be
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