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Merck

217964

Sigma-Aldrich

Tetrabutylammonium-tetrafluoroborat

99%

Synonym(e):

Ammonium tetra-n-butyl tetrafluoroborate

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About This Item

Lineare Formel:
(CH3CH2CH2CH2)4N(BF4)
CAS-Nummer:
Molekulargewicht:
329.27
Beilstein:
3577508
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352116
PubChem Substanz-ID:
NACRES:
NA.22

Qualitätsniveau

Assay

99%

Form

powder

mp (Schmelzpunkt)

155-161 °C (lit.)

Löslichkeit

methanol: soluble 10%, clear, colorless

SMILES String

F[B-](F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1

InChIKey

NNZZSJSQYOFZAM-UHFFFAOYSA-N

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Allgemeine Beschreibung

Tetrabutylammonium tetrafluoroborate is used as an electrolyte for the series of arylketone synthesis.

Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.

Anwendung

Used to prepare other tetrabutylammonium salts in aqueous solutions. Electrolyte additive in the synthesis of conducting poly(thiophenes).

Piktogramme

CorrosionExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

No data available

Flammpunkt (°C)

No data available

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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Preparation and properties of novel polythiophenes containing 1,3-dithiol-2-ylidene moieties.
Kozaki M, et al.
The Journal of Organic Chemistry, 59(2), 442-450 (1994)
Marco Antonio Balbino et al.
Forensic science international, 221(1-3), 29-32 (2012-04-25)
A new voltammetric method for the determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC) is described. The voltammetric experiments were accomplished in N-N dimethylformamide/water (9:1, v/v), using tetrabutylammonium tetrafluoroborate (TBATFB) 0.1mol/L as supporting electrolyte and a glassy carbon disk electrode as the working electrode.
Agnieszka Stolarczyk et al.
Sensors (Basel, Switzerland), 19(5) (2019-03-07)
In this study, polycarbazole (PCz) is presented as a receptor structure for chemoresistive hydrogen sensors. The fabrication of the proposed sensors via electropolymerisation of PCz on interdigitated Pt electrodes is an inexpensive, cost-efficient, and repeatable method. Preliminary results presented in
Rajesh G Pillai et al.
Langmuir : the ACS journal of surfaces and colloids, 27(14), 9028-9033 (2011-06-23)
Spontaneous self-assembly of alkylthiosulfates on gold produce monolayers similar to the corresponding alkanethiols. Alkylthiosulfate self-assembly from THF solutions is inhibited in the presence of tetrabutylammonium tetrafluoroborate electrolyte. The mechanism of alkylthiosulfate self-assembly and the role of electrolyte and trace water
José Antonio Morales-Serna et al.
Organic & biomolecular chemistry, 8(21), 4940-4948 (2010-09-08)
A facile and mild macrolactonization reaction of ω-hydroxy acids was developed based on the transesterification of benzotriazole esters. Treatment of ω-hydroxy acids with 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) and 1-hydroxy benzotriazole (HOBT) in chloroform provided macrolactones in excellent yields. The reactions were

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