208264

Allyltrimethylsilan

98%

• Synonym(e): 3-(Trimethylsilyl)-propen
• Lineare Formel: H₂C=CHCH₂Si(CH₃)₃
• CAS-Nummer: 762-72-1
• Molekulargewicht: 114.26
• Beilstein: 906755
• EG-Nummer: 212-104-5
• MDL-Nummer: MFCD00008635
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24852502
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.407 (lit.)
• bp: 84-88 °C (lit.)
• Dichte: 0.719 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: C[Si](C)(C)CC=C
• InChI: 1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
• InChIKey: HYWCXWRMUZYRPH-UHFFFAOYSA-N

Beschreibung

Anwendung

Allyltrimethylsilane is a general reagent to introduce allyl groups across acid chlorides, aldehydes, ketones, iminium ions, enones, and for cross-coupling with other carbon electrophiles. It is used as a reagent in Hosomi−Sakurai reaction.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Danger
• H-Sätze: H225,H315
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353
• Gefahreneinstufungen: Flam. Liq. 2 - Skin Irrit. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 60.8 °F - closed cup
• Flammpunkt (°C): 16 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter