163821

3-Methoxy-2-nitrobenzaldehyd

≥97%

• Lineare Formel: CH₃OC₆H₃(NO₂)CHO
• CAS-Nummer: 53055-05-3
• Molekulargewicht: 181.15
• Beilstein: 1959385
• EG-Nummer: 258-332-9
• MDL-Nummer: MFCD00007135
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24850038
• NACRES: NA.22

Eigenschaften

• Assay: ≥97%
• Form: solid
• mp (Schmelzpunkt): 97-101 °C (lit.)
• SMILES String: [H]C(=O)c1cccc(OC)c1[N+]([O-])=O
• InChI: 1S/C8H7NO4/c1-13-7-4-2-3-6(5-10)8(7)9(11)12/h2-5H,1H3
• InChIKey: GDTUACILWWLIJF-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

3-Methoxy-2-nitrobenzaldehyde undergoes 1,4-diazabicyclo[2.2.2]octane-catalyzed reaction with methyl vinyl ketone (MVK) to afford normal Baylis-Hillman adduct, the MVK dimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts.

Anwendung

3-Methoxy-2-nitrobenzaldehyde was used in the synthesis of 8-hydroxyquinazoline, methy-3-methoxyanthranilate and 3-methoxy-2-nitrobenzylidenebisformamide.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)