147338
Benzylidenmalononitril
98%
Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(2)
About This Item
Lineare Formel:
C6H5CH=C(CN)2
CAS-Nummer:
Molekulargewicht:
154.17
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
98%
mp (Schmelzpunkt)
83-85 °C (lit.)
Funktionelle Gruppe
nitrile
phenyl
SMILES String
N#C\C(=C/c1ccccc1)C#N
InChI
1S/C10H6N2/c11-7-10(8-12)6-9-4-2-1-3-5-9/h1-6H
InChIKey
WAVNYPVYNSIHNC-UHFFFAOYSA-N
Allgemeine Beschreibung
Benzylidenemalononitrile undergoes rapid and catalyst-free solid/vapor reaction with primary alkyl amines to yield N-benzylidene-amine. It undergoes addition reaction with octyl- and decylzirconocene chloride. It is a potential substrate for soluble methane monooxygenase.
Anwendung
Benzylidenemalononitrile was used in fluorescence-based assay for determination of soluble methane monooxygenase activity in solution.
Signalwort
Warning
Gefahreneinstufungen
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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A R Miller et al.
Applied microbiology and biotechnology, 58(2), 183-188 (2002-03-06)
A fluorescence-based assay was developed to estimate soluble methane monooxygenase (sMMO) activity in solution. Whole cells of Methylosinus trichosporium OB3b expressing sMMO were used to oxidize various compounds to screen for fluorescent products. Of the 12 compounds tested, only coumarin
Liqi Shi et al.
Chemical communications (Cambridge, England), 50(7), 872-874 (2013-12-04)
A new rapid and catalyst-free solid/vapor reaction between benzylidenemalonate/benzylidenemalononitrile and primary alkyl amines was found. With these as sensory units of fluorescent polymers, probes for primary amine vapor with high sensitivity and selectivity were developed.
Yuanhong Liu et al.
The Journal of organic chemistry, 67(20), 7019-7028 (2002-10-02)
Direct addition of alkylzirconocenes to activated alkenes was found, for the first time. Octyl- and decylzirconocene chloride reacted with benzylidenemalononitrile to give the corresponding addition products after hydrolysis in 86% and 79% yield, respectively. Zirconacyclopentanes showed a similar reactivity toward
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