126721

Hydrazobenzol

• Synonym(e): N,N′-Diphenylhydrazin, N,N′-Bianilin, NSC 3510
• Lineare Formel: C₆H₅NHNHC₆H₅
• CAS-Nummer: 122-66-7
• Molekulargewicht: 184.24
• Beilstein: 639793
• EG-Nummer: 204-563-5
• MDL-Nummer: MFCD00003012
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24847740
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 200
• mp (Schmelzpunkt): 123-126 °C (lit.)
• SMILES String: N(Nc1ccccc1)c2ccccc2
• InChI: 1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H
• InChIKey: YBQZXXMEJHZYMB-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Hydrazobenzene has been prepared by the reduction of azobenzene by SmI(2) in THF.

Hydrazobenzene is an intermediate in the hydrogenation of azoxybenzene to aniline.

Anwendung

Reactant involved in:

• Insertion reactions with organometallic tantalum complexes
• Reduction reactions catalyzed by titanium(III) trichloride yielding amines
• Studying the mechanism of hydrazobenzene rearrangement
• Reaction with N-heterocyclic stable silylene
• Synthesis of dimanganese amide hydrazide cluster complexes
• Iron-mediated hydrazine reductions yielding iron arylimide cubanes

Sonstige Hinweise

Contains varying amounts of azobenzene

Sicherheitshinweise

• Piktogramme: GHS08,GHS07,GHS09
• Signalwort: Danger
• H-Sätze: H302,H350,H410
• P-Sätze: P201 - P273 - P301 + P312 + P330 - P308 + P313
• Gefahreneinstufungen: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges