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125571

Sigma-Aldrich

5-Chlor-2-mercaptobenzothiazol

technical grade, ≥90%

Synonym(e):

5-Chlor-2-benzothiazolthiol, CMBT

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About This Item

Empirische Formel (Hill-System):
C7H4ClNS2
CAS-Nummer:
5331-91-9
Molekulargewicht:
201.70
EG-Nummer:
226-235-0
MDL-Nummer:
MFCD00005783
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24847675
NACRES:
NA.22

Qualität

technical grade

Qualitätsniveau

200

Assay

≥90%

mp (Schmelzpunkt)

198-200 °C (lit.)

Funktionelle Gruppe

chloro

SMILES String

Sc1nc2cc(Cl)ccc2s1

InChI

1S/C7H4ClNS2/c8-4-1-2-6-5(3-4)9-7(10)11-6/h1-3H,(H,9,10)

InChIKey

NKYDKCVZNMNZCM-UHFFFAOYSA-N

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Allgemeine Beschreibung

5-Chloro-2-mercaptobenzothiazole(CMBZT) reacts with iodine in a molar ratio of 1:1 to form charge-transfer complex (CMBZT)I2.

Anwendung

5-Chloro-2-mercaptobenzothiazole (CMBZT) has been used in the analysis of lipopolysaccharide by negative-ion matrix-assisted laser desorption ionization-time of flight mass spectrometry. It has been used in the synthesis of the new mixed ligand silver(I) chloride complex with the heterocyclic thioamide CMBZT and tri(p-tolyl)phosphine. Found to be more sensitive than DHB for analysis of high mannose N-linked glycans. Used in analysis of peptidoglycan muropeptides.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
BCBF0818V
BCBF0818
1439185
04921PH
7901KK

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Chen Chen et al.
Biotechnology for biofuels, 11, 155-155 (2018-07-12)
Polysaccharide monooxygenases (PMOs) of the auxiliary activity 9 (AA9) family have been reported to oxidize C1, C4, and C6 positions in cellulose. However, currently no direct evidence exists that PMOs oxidize C6 positions in cellulose, and molecular mechanism of C1, C4
Adeline M Hajjar et al.
Infection and immunity, 74(12), 6730-6738 (2006-09-20)
Francisella tularensis is an intracellular gram-negative bacterium that is highly infectious and potentially lethal. Several subspecies exist of varying pathogenicity. Infection by only a few organisms is sufficient to cause disease depending on the model system. Lipopolysaccharide (LPS) of gram-negative
Synthesis and Characterization of (PTU) I2 (PTU= 6-n-propyl-2-thiouracil) and (CMBZT) I2 (CMBZT= 5-chloro-2-mercaptobenzothiazole) and Possible Implications for the Mechanism of Action of Anti-Thyroid Drugs.
Antoniadis CD, et al.
European Journal of Inorganic Chemistry, 2003(8), 1635-1640 (2003)
L Kyros et al.
Bioinorganic chemistry and applications, 386860-386860 (2010-04-10)
The synthesis and characterization of the silver(I) chloride complex of formula {[AgCI(CMBZT)(TPTP)(2)] . (MeOH)} (1) (CMBZT = 5-chloro-2-mercaptobenzothiazole, TPTP = tris(p-tolyl)phosphine) is described. Also the structure of the hydrate derivative {[AgCI(TPTP)(3)] . (0.5 . H(2)O)} (2) of the corresponding known
Ariadna Fernández-Calvet et al.
Scientific reports, 8(1), 6872-6872 (2018-05-04)
Airway infection by nontypeable Haemophilus influenzae (NTHi) associates to chronic obstructive pulmonary disease (COPD) exacerbation and asthma neutrophilic airway inflammation. Lipids are key inflammatory mediators in these disease conditions and consequently, NTHi may encounter free fatty acids during airway persistence.
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Methods and Matrices for Mass Spectrometry of Glycans

Glycosylation is known to have profound influence on various physiochemical, cellular and biological functions of proteins. Alterations in this modification are known to affect the immune system and have been associated with various pathological states such as cancer, rheumatoid arthritis, and inflammatory diseases.

Methods and matrices for mass spectrometry of glycans

Mass Spectrometry of Glycans, method comparison and products

Protokolle

Mass Spectrometry of Glycans

Mass Spectrometry of Glycans

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