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Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate.

Chemical communications (Cambridge, England) (2005-03-10)
Christian Böing, Giancarlo Franciò, Walter Leitner
RÉSUMÉ

Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.

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Sigma-Aldrich
Diethyl diallylmalonate, 98%