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40799

Supelco

Prothiofos

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Formule empirique (notation de Hill):
C11H15Cl2O2PS2
Numéro CAS:
Poids moléculaire :
345.25
Numéro Beilstein :
1998314
Numéro MDL:
Code UNSPSC :
41116107
Nomenclature NACRES :
NA.24

Qualité

certified reference material
TraceCERT®

Niveau de qualité

Gamme de produits

TraceCERT®

Durée de conservation

limited shelf life, expiry date on the label

Fabricant/nom de marque

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Température de stockage

−20°C

Chaîne SMILES 

CCCSP(=S)(OCC)Oc1ccc(Cl)cc1Cl

InChI

1S/C11H15Cl2O2PS2/c1-3-7-18-16(17,14-4-2)15-11-6-5-9(12)8-10(11)13/h5-6,8H,3-4,7H2,1-2H3

Clé InChI

FITIWKDOCAUBQD-UHFFFAOYSA-N

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Description générale

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma aldrich.com

Prothiofos is a non-systemic insecticide and belongs to the group of organophosphates. It is an acetylcholinesterase (AChE) inhibitor causing hyperexcitation and impedes the functioning of the nervous system. Prothiofos gets activated by contact and ingestion and is used to control caterpillars, Pseudococcus spp., thrips, cockchafer larvae, cutworms, etc. in vegetables, fruit, maize, sugar cane, sugar beets, tea, tobacco, and ornamentals.
According to the Commission Implementing Regulation (EU) No 2076/2002 of 20th November 2002, prothiofos is not approved for use in the European Union (EU) as a plant protection agent, following Regulation (EC) No. 1107/2009. But a default maximum residue limit of 0.01 mg/kg is applicable for the presence of prothiofos in products of plant and animal origin, according to Art 18(1)(b) Reg 396/2005.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Prothiofos CRM may also be used as given below:

  • Multi-residue analysis of 160 multiclass pesticides using ethyl acetate (EtAC)/n. hexane mixture for extraction from chamomile, thyme, and marjoram samples and their analysis by gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Evaluation of an automated QuEChERS procedure for the determination of 270 pesticides residues in celery, eggplant, tomato, leek, green tea, corn, grape, and soybean oil samples using liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS)
  • Gas chromatographic-mass spectrometric (GC/MS) analysis of six organophosphorus (OPPs) pesticides in bell pepper samples after a QuEChERS-citrate method based sample extraction
  • Simultaneous determination of 300 pesticide residues in human hair samples by LC- and GC-MS/MS
  • Quantification of 255 pesticide residues in vegetable oil samples using modified QuEChERS with GC-MS/MS based method
  • Method development to determine 133 pesticide residues in Chenpi samples using a modified QuEChERS method based on ―NH2 sorbent and gas chromatography-tandem mass spectrometry (GC-MS/MS)

Produits recommandés

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Informations légales

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Skull and crossbonesEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Eunyoung Park et al.
Chemosphere, 277, 130215-130215 (2021-03-29)
Multiresidual pesticide analysis in hair can provide useful perspectives on the relationship between pesticides and human health. To establish a rapid and simultaneous analytical method using LC-MS/MS and GC-MS/MS, optimization of hair pulverization, extraction solvent and purification with dispersive SPE
Zeying He et al.
Analytical and bioanalytical chemistry, 409(4), 1017-1030 (2016-11-14)
In this study, a simple and high-throughput method for determination of 255 pesticides in vegetable oils was developed based on QuEChERS sample preparation method combined with gas chromatography-triple quadrupole mass spectrometry. Different clean-up approaches were tested: A, 150 mg PSA + 150 mg C18;

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