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40152-U

4-Chlorotoluene solution

Name: 4-Chlorotoluene solution
Brand: SUPELCO

5000 μg/mL in methanol, analytical standard

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About This Item

Numéro CAS:

106-43-4

Code UNSPSC :

77101502

Nomenclature NACRES :

NA.24

Qualité

analytical standard

Conditionnement

ampule of 1 mL

Concentration

5000 μg/mL in methanol

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

environmental

Format

single component solution

Température de stockage

2-8°C

InChI

1S/C7H7Cl/c1-6-2-4-7(8)5-3-6/h2-5H,1H3

Clé InChI

NPDACUSDTOMAMK-UHFFFAOYSA-N

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Pictogrammes

GHS02,GHS06,GHS08

Mention d'avertissement

Danger

Mentions de danger

H225,H301 + H311 + H331,H370

Conseils de prudence

P210 - P260 - P280 - P301 + P310 - P311

Classification des risques

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

51.8 °F - closed cup

Point d'éclair (°C)

11 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves

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Certificats d'analyse (COA)

Lot/Batch Number

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Oxidation of p-chlorotoluene and cyclohexene catalysed by polymer-anchored oxovanadium(IV) and copper(II) complexes of amino acid derived tridentate ligands.

Mannar R Maurya et al.

Dalton transactions (Cambridge, England : 2003), (32)(32), 4220-4232 (2008-08-07)

3-Formylsalicylic acid (Hfsal), covalently bound to chloromethylated polystyrene (PS) and cross-linked with 5% divinylbenzene reacts with d,l-alanine and l-isoleucine to give the Schiff-base tridentate ligands PS-H(2)fsal-d,l-Ala and PS-H(2)fsal-l-Ile, respectively. These anchored ligands upon reaction with VOSO(4) and Cu(CH(3)COO)(2).H(2)O form the

Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation.

Eric R Strieter et al.

Journal of the American Chemical Society, 125(46), 13978-13980 (2003-11-13)

A comparative kinetic examination of catalyst systems based on several monophosphinobiaryl ligands is reported. The bulk of the phosphine ligand controls the catalytic activity and the rate of catalyst activation with the catalyst based on 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl providing the greatest activity

Vibrational spectroscopic (FT-IR and FT-Raman), first-order hyperpolarizablity, HOMO, LUMO, NBO, Mulliken charges and structure determination of 2-bromo-4-chlorotoluene.

C Arunagiri et al.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 1747-1756 (2011-06-18)

The FT-IR and FT-Raman spectra of 2-bromo-4-chlorotoluene (2B4CT) molecule have been recorded in the region 4000-400 cm(-1) and 3500-50 cm(-1), respectively. Optimized geometrical structures, harmonic vibrational frequencies, intensities, reduced mass, force constants and depolarization ratio have been computed by the

Multireference calculations of the fluorescence, phosphorescence and photodissociation of p-chlorotoluene.

Ya-Jun Liu et al.

Physical chemistry chemical physics : PCCP, 7(23), 3938-3942 (2005-12-07)

Equilibrium geometries and vibrational frequencies of the ground and some excited states of p-chlorotoluene were calculated by the complete active space self-consistent field (CASSCF) method. Multi-reference CASSCF second order perturbation theory (MSCASPT2) calculations were performed on the vertical excitation energies

Biotransformations catalyzed by cloned p-cymene monooxygenase from Pseudomonas putida F1.

T Nishio et al.

Applied microbiology and biotechnology, 55(3), 321-325 (2001-05-09)

p-Cymene monooxygenase (CMO) from Pseudomonas putida F1 consists of a hydroxylase (CymA1) and a reductase component (CymA2) which initiate pcymene (p-isopropyltoluene) catabolism by oxidation of the methyl group to p-isopropylbenzyl alcohol (p-cumic alcohol). To study the possible diverse range of

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