938750

GPhos ChemBeads

• Synonyme(s) : (3-(tert-Butoxy)-2′,6′-diisopropyl-6-methoxy-[1,1′-biphenyl]-2-yl)dicyclohexylphosphane ChemBeads
• Formule empirique (notation de Hill): C₃₅H₅₃O₂P
• Numéro CAS: 2489243-29-8
• Poids moléculaire : 536.77
• Numéro MDL: MFCD32857529
• Code UNSPSC : 12352100

Propriétés

• Forme: solid
• Niveau de qualité: 100
• Composition: loading of catalyst, 4-6 wt. %
• Capacité de réaction: reaction type: Cross Couplings
• Pertinence de la réaction: reagent type: catalyst; reagent type: ligand
• Pf: 230-233 °C
• Groupe fonctionnel: phosphine
• Chaîne SMILES: CC(C(C=CC=C1C(C)C)=C1C2=C(OC)C=CC(OC(C)(C)C)=C2P(C3CCCCC3)C4CCCCC4)C
• InChI: 1S/C35H53O2P/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27/h15,20-27H,9-14,16-19H2,1-8H3

Description

Description générale

GPhos is a Buchwald-type ligand used in various cross-coupling reactions.

Application

GPhos is a dialkylbiaryl monophosphine ligand developed by the Buchwald group for aryl amination reactions. The GPhos Pd oxidative addition complex (OAC) enables room temperature C-N couplings with complex substrates at higher efficiency than previously developed ligands.

Learn more about Buchwald Phosphine Ligands

For general uses, product is also available in powdered form (918008)

Caractéristiques et avantages

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable