402869

Chloramine T trihydrate

ACS reagent, 98%

• Synonyme(s) : N-Chloro-p-toluenesulfonamide sodium salt
• Formule linéaire : CH₃C₆H₄SO₂NClNa · 3H₂O
• Numéro CAS: 7080-50-4
• Poids moléculaire : 281.69
• Numéro Beilstein : 3924168
• Numéro CE : 204-854-7
• Numéro MDL: MFCD00149066
• Code UNSPSC : 12352100
• ID de substance PubChem : 24865128
• Nomenclature NACRES : NA.21

Propriétés

• Qualité: ACS reagent
• Niveau de qualité: 200
• Pureté: 98%; 98.0-103.0% (ACS specification)
• Forme: powder
• Pertinence de la réaction: reagent type: oxidant
• Impuretés: <1.5% insolubles (alcohol)
• pH: 8.0-10.0 (25 °C, 5%)
• Pf: 167-170 °C (lit.)
• Solubilité: H₂O: passes test
• Adéquation: passes test for determination of bromide
• Chaîne SMILES: O.O.O.Cc1ccc(cc1)S(=O)(=O)N([Na])Cl
• InChI: 1S/C7H7ClNO2S.Na.3H2O/c1-6-2-4-7(5-3-6)12(10,11)9-8;;;;/h2-5H,1H3;;3*1H2/q-1;+1;;;
• Clé InChI: NZYOAGBNMCVQIV-UHFFFAOYSA-N

Description

Description générale

Chloramine T (CAT) trihydrate is a commonly used reagent for organic synthesis especially in heterocyclic chemistry. CAT is an active chlorine compound that shows antimicrobial activity.

Application

Chloramine T trihydrate may be used as an oxidizing agent in the synthesis of 8-chloro-[1,2,4]triazolo[4,3-a]pyrazine derivatives and novel isoxazolines.
It may also be used in the synthesis of the following compounds:

• Nitrile imines by the oxidative dehydrogenation of N-(nitrobenzyl)-imidazole aldehyde hydrazine.
• Mono-N-tosylated-1,2-diamines.
• 3,5-Disubstituted isoxazoles.
• Fused 3,6-disubstituted triazolothiadiazoles by the oxidative cyclization of N-heteroaryl-substituted hydrazones.

Nitrene source for aziridinations and aminohydroxylations.

Conditionnement

Capable of oxidative cyclization to produce various heterocycles.

Informations sur la sécurité

• Pictogrammes: GHS08,GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H302,H314,H334
• Conseils de prudence: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B
• Risques supp: EUH031
• Code de la classe de stockage: 8A - Combustible corrosive hazardous materials
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 377.6 °F - closed cup
• Point d'éclair (°C): 192 °C - closed cup