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Autres documents

32979

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N-(6-Chloro-3-pyridylmethyl)-N′-cyano-acetamidine

PESTANAL®, analytical standard

Synonyme(s) :

N-(6-Chloro-3-pyridylmethyl)-N′-cyano-acetamidine

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About This Item

Formule empirique (notation de Hill):
C9H9ClN4
Numéro CAS:
190604-92-3
Poids moléculaire :
208.65
Numéro MDL:
MFCD08690484
Code UNSPSC :
41116107
ID de substance PubChem :
329754419
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

100

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
environmental

Format

neat

Chaîne SMILES 

C\C(NCc1ccc(Cl)nc1)=N/C#N

InChI

1S/C9H9ClN4/c1-7(14-6-11)12-4-8-2-3-9(10)13-5-8/h2-3,5H,4H2,1H3,(H,12,14)

Clé InChI

AYEAUPRZTZWBBF-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Acetamiprid-N-desmethyl is a metabolite of the neonicotinoid insecticide, acetamiprid.

Application

Acetamiprid-N-desmethyl may be used as a reference standard in the determination of acetamiprid-N-desmethyl in urine samples using ultra high-performance liquid chromatography coupled with orbitrap high resolution mass spectrometry (UHPLC-HRMS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Autres remarques

Acetamipride-Metabolite IM-2-1

Produits recommandés

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Skull and crossbones
GHS06

Mention d'avertissement

Danger

Mentions de danger

H301 - H315 - H319 - H335

Classification des risques

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
BCCJ0865
BCCD1153
BCBV6075
BCBV6076
BCBQ5906V

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Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

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Relationship between urinary N-desmethyl-acetamiprid and typical symptoms including neurological findings: a prevalence case-control study
Marfo TJ, et al.
PLoS ONE, 10(11), e0142172-e0142172 (2015)
Richard C Kolanczyk et al.
Xenobiotica; the fate of foreign compounds in biological systems, 50(7), 805-814 (2019-11-15)
Providing an alternative to pyrethroids, organophosphates, and carbamates, the neonicotinoids are now the most widely used insecticides in the world. They are water soluble and relatively stable in soil and water which allows for run-off through surface waters and thus
Takamitsu Otake et al.
Journal of AOAC International, 103(6), 1469-1477 (2020-11-29)
Neonicotinoid insecticides (neonicotinoids) are widely used, however, they can negatively affect human health. Thus, neonicotinoids and their metabolites in human urine are analyzed globally to assess exposure levels and health risks. To properly assess the exposure levels and health risks
Mohammad Faraji et al.
Food chemistry, 240, 634-641 (2017-09-28)
A QuEChERS based methodology was developed for the simultaneous identification and quantification of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio by liquid chromatography-tandem mass spectrometry for the first time. First, sample extraction was done with MeCN:citrate buffer:NaHCO
Jianbo Hou et al.
Food chemistry, 270, 204-213 (2018-09-04)
An analytical method based on liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for the first simultaneous determination of ten neonicotinoid insecticides (pymetrozine, dinotefuran, nitenpyram, thiamethoxam, flonicamid, imidacloprid, clothianidin, imidaclothiz, acetamiprid, thiacloprid) and two metabolites (4-trifluoromethylnicotinamide and N-desmethylacetamiprid) in honey
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Protocoles

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Banned and Other Neonicotinoids from Plant Material

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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