8.20315

1-Chloronaphthalene

for synthesis

• Synonyme(s) : 1-Chloronaphthalene, α-Naphthyl chloride
• Formule empirique (notation de Hill): C₁₀H₇Cl
• Numéro CAS: 90-13-1
• Poids moléculaire : 162.62
• Numéro MDL: MFCD00003874
• Code UNSPSC : 12352101
• Numéro de classement CE : 201-967-3
• Nomenclature NACRES : NA.22

Propriétés

• Pression de vapeur: 0.05 hPa ( 20 °C)
• Niveau de qualité: 200
• Pureté: 85.0-88.0% (GC)
• Forme: liquid
• Température d'inflammation spontanée: >500 °C
• Puissance: 1540 mg/kg LD₅₀, oral (Rat); >2000 mg/kg LD₅₀, skin (Rat)
• Indice de réfraction: n20/589 1.6332
• pH: 7 (20 °C in H₂O, undiluted)
• Point d'ébullition: 259 °C/1013 hPa
• Pf: -6--2.5 °C
• Température de transition: flash point 115 °C
• Densité: 1.19 g/cm³ at 20 °C
• Température de stockage: 2-30°C
• InChI: 1S/C10H7Cl/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
• Clé InChI: JTPNRXUCIXHOKM-UHFFFAOYSA-N

Description

Application

• Enhancement of polymer solar cells: 1-Chloronaphthalene was used as a solid additive in high-efficiency polymer solar cells developed with a benzo-difuran-based donor polymer, improving device performance and stability (Chen et al., 2023).
• Study of charge transfer complexes: The electronic and vibrational properties of tetracyanoethylene-chloronaphthalene charge transfer complex in solution were explored using TD-DFT and ab initio molecular dynamics, providing insights into molecular interactions and stability (Coppola et al., 2022).
• Efficiency boost in solar cells: 1-Chloronaphthalene was employed as a nontoxic, halogen-free additive in polymer solar cells, significantly boosting their efficiency and highlighting its potential as an environmentally friendly material for solar energy applications (Liu et al., 2021).
• Development of nonhalogenated-solvent solar cells: Medium-band-gap small-molecule acceptors based on a 6,12-dihydro-diindolo[1,2-b:1,2-e]pyrazine unit were used in nonhalogenated-solvent-processed polymer solar cells, where 1-Chloronaphthalene acted as a solvent, promoting higher device efficiencies and reduced environmental impact (Chen et al., 2019).

Remarque sur l'analyse

Assay (GC, area%): 85.0 - 88.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.188 - 1.195
2-Chloronaphthalene (GC, area%): 12.0 - 15.0 % (a/a)
Identity (IR): passes test

Informations sur la sécurité

• Pictogrammes: GHS07,GHS09
• Mention d'avertissement: Warning
• Mentions de danger: H302 - H315 - H319 - H335 - H400
• Conseils de prudence: P261 - P264 - P273 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 249.8 °F - closed cup
• Point d'éclair (°C): 121 °C - closed cup