ALD00386

Fe(dibm)₃

• Synonyme(s) : Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)
• Formule empirique (notation de Hill): C₂₇H₄₅FeO₆
• Numéro CAS: 24444-72-2
• Poids moléculaire : 521.49
• Code UNSPSC : 12161600
• ID de substance PubChem : 329772664
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solid
• Niveau de qualité: 100
• Pertinence de la réaction: core: iron; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 96-102 °C
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.[Fe+3]
• InChI: 1S/3C9H15O2.Fe/c3*1-6(2)8(10)5-9(11)7(3)4;/h3*5-7H,1-4H3;/q3*-1;+3
• Clé InChI: LKNJSJQVZKKQHU-UHFFFAOYSA-N

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.

Autres remarques

The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling

Functionalized olefin cross-coupling to construct carbon–carbon bonds

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable