911402

(CyPAd-DalPhos)NiCl(otol)

≥95%

• Synonyme(s) : 8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
• Formule empirique (notation de Hill): C₃₅H₄₉ClNiO₃P₂
• Numéro CAS: 2115838-60-1
• Poids moléculaire : 673.86
• Code UNSPSC : 12352200
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: ≥95%
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; reaction type: Cross Couplings
• Pf: 193-197 °C

Description

Application

(CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp²)-O coupling and N-arylation reactions.

Autres remarques

Technology Spotlight: DalPhos ligands

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

Informations sur la sécurité

• Pictogrammes: GHS08,GHS07,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H302 + H312 + H332,H341,H351,H372,H410
• Conseils de prudence: P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
• Classification des risques: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation
• Organes cibles: Respiratory Tract,Skin
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable