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900416

Sigma-Aldrich

Nitrogen-doped graphene

Synonyme(s) :

N-Doped graphene, NDG, NG

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About This Item

Code UNSPSC :
12352200

Forme

powder

Composition

Carbon, >80 wt. %
Nitrogen, >4 wt. %

Couleur

black

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Description générale

This highly exfoliated nitrogen-doped graphene exhibits high electrochemical activity towards oxygen reduction in alkali medium providing an affordable industrial alternative to currently used noble metal-based catalysts (i.e. Pt, Pd). This nitrogen-doped graphene shows high onset potential (ca. 940 mV vs. RHE) carrying out the electrochemical oxygen reduction reaction (ORR) towards a 4 electron pathway avoiding the production of H2O2. Furthermore, this material is reported to be more stable (to MeOH) and durable (CO tolerance) than Pt-based catalysts.This highly exfoliated nitrogen-doped graphene exhibits high electrochemical activity towards oxygen reduction in alkali medium providing an affordable industrial alternative to currently used noble metal-based catalysts (i.e. Pt, Pd). This nitrogen-doped graphene shows high onset potential (ca. 940 mV vs. RHE) carrying out the electrochemical oxygen reduction reaction (ORR) towards a 4 electron pathway avoiding the production of H2O2. Furthermore, this material is reported to be more stable (to MeOH) and durable (CO tolerance) than Pt-based catalysts.

Propriétés physiques

Electrocatalytic oxygen reduction reaction (ORR) onset potential: >-0.1 V (0.1 M KOH vs Ag/AgCl).

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
MKCC2706

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Facile synthesis of mesoporous nitrogen-dopedgraphene: An efficient methanol?tolerantcathodiccatalystfor oxygen reductionreaction.
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Physical chemistry chemical physics : PCCP, 16(3), 1060-1066 (2013-11-30)
Chemical doping of nitrogen into graphene can significantly enhance the reversible capacity and cyclic stability of the graphene-based lithium ion battery (LIB) anodes, and first principles calculations based on density functional theory suggested that pyridinic-N shows stronger binding with Li
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