441058

(1R)-(−)-Menthyl acetate

98%

• Synonyme(s) : (-)-Menthol acetate, (-)-Menthyl acetate, (-)-p-Menthyl acetate, (1R,2S,5R)-5-Methyl-2-(1-methylethyl)cyclohexanol acetate, Acetic acid (R)-menthyl ester, L-Menthyl acetate, l-(-)-Menthyl acetate, l-Menthol acetate
• Formule empirique (notation de Hill): C₁₂H₂₂O₂
• Numéro CAS: 2623-23-6
• Poids moléculaire : 198.30
• Numéro Beilstein : 2208505
• Numéro CE : 220-076-0
• Numéro MDL: MFCD00001482
• Code UNSPSC : 12352108
• ID de substance PubChem : 24867639
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Pureté: 98%
• Forme: liquid
• Activité optique: [α]20/D −81°, c = 8 in benzene
• Pureté optique: ee: 98% (GLC)
• Indice de réfraction: n20/D 1.447 (lit.)
• Point d'ébullition: 229-230 °C (lit.)
• Densité: 0.92 g/mL at 25 °C (lit.)
• Groupe fonctionnel: ester
• Chaîne SMILES: CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O
• InChI: 1S/C12H22O2/c1-8(2)11-6-5-9(3)7-12(11)14-10(4)13/h8-9,11-12H,5-7H2,1-4H3/t9-,11+,12-/m1/s1
• Clé InChI: XHXUANMFYXWVNG-ADEWGFFLSA-N

Description

Application

• RIFM fragrance ingredient safety assessment, menthyl acetate (isomer unspecified): This safety assessment covers the toxicity data on menthyl acetate, indicating low toxicity and providing a foundation for safe usage in fragrances and related products (AM Api et al., 2017).


• The crystalline sponge method: MOF terminal ligand effects: This article discusses the inclusion of (1R)-(−)-menthyl acetate into Metal-Organic Frameworks (MOFs) and analyzes its interactions and structural integration (TR Ramadhar et al., 2015).


• Engineering a Bacillus subtilis esterase for selective hydrolysis of d, l-menthyl acetate in an organic solvent-free system: This research engineered a variant of Bacillus subtilis esterase that shows enhanced selectivity and efficiency in the hydrolysis of d, l-menthyl acetate, suitable for industrial applications (J Qiao et al., 2023).

Informations sur la sécurité

• Pictogrammes: GHS09
• Mentions de danger: H411
• Conseils de prudence: P273 - P391 - P501
• Classification des risques: Aquatic Chronic 2
• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 170.6 °F - closed cup
• Point d'éclair (°C): 77 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Gloves, type ABEK (EN14387) respirator filter