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440914

Sigma-Aldrich

2,2′-Azobis(2-methylpropionamidine) dihydrochloride

powder or granules, 97%

Synonyme(s) :

AAPH

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About This Item

Formule linéaire :
[=NC(CH3)2C(=NH)NH2]2·2HCl
Numéro CAS:
2997-92-4
Poids moléculaire :
271.19
Numéro Beilstein :
3718854
Numéro CE :
221-070-0
Numéro MDL:
MFCD00142725
Code UNSPSC :
12162002
ID de substance PubChem :
24867630
Nomenclature NACRES :
NA.23

Niveau de qualité

200

Pureté

97%

Forme

powder or granules

t1/2

10 hr(56 °C)

Pf

175-177 °C (lit.)

Solubilité

acetone, dioxane, methanol, ethanol, DMSO and water: soluble

Chaîne SMILES 

Cl.Cl.CC(C)(\N=N\C(C)(C)C(N)=N)C(N)=N

InChI

1S/C8H18N6.2ClH/c1-7(2,5(9)10)13-14-8(3,4)6(11)12;;/h1-4H3,(H3,9,10)(H3,11,12);2*1H/b14-13+;;

Clé InChI

LXEKPEMOWBOYRF-QDBORUFSSA-N

Catégories apparentées

Application

Free radical initiator.
Polymerization initiator for acrylic, vinyl and allyl monomers.

Caractéristiques et avantages

Undergoes first order decomposition to a cationic radical. Decomposes on exposure to UV. Compatible with cationic surfactants. Decomposition rate is pH dependent

Pictogrammes

FlameExclamation markEnvironment
GHS02,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H251,H302,H317,H319,H410

Classification des risques

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Self-heat. 1 - Skin Sens. 1

Code de la classe de stockage

4.2 - Pyrophoric and self-heating hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
MKCP4036
WXBD4809V
MKCL4411
WXBC9715V
MKCF7292

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Olivier Mozziconacci et al.
Chemical research in toxicology, 25(9), 1842-1861 (2012-06-21)
Glutathione thiyl radicals (GS(•)) were generated in H(2)O and D(2)O by either exposure of GSH to AAPH, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH
Rong-Rong He et al.
PloS one, 8(3), e57732-e57732 (2013-03-08)
It is now well established that the developing embryo is very sensitive to oxidative stress, which is a contributing factor to pregnancy-related disorders. However, little is known about the effects of reactive oxygen species (ROS) on the embryonic cardiovascular system
A Nakajima et al.
Analytical and bioanalytical chemistry, 403(7), 1961-1970 (2012-05-01)
The characteristics of the spin-trapping reaction in the oxygen radical absorbance capacity (ORAC)-electron spin resonance (ESR) assay were examined, focusing on the kind of spin traps. 2,2-Azobis(2-amidinopropane) dihydrochloride (AAPH) was used as a free radical initiator. The spin adducts of
Ju-Young Ko et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 52, 113-120 (2012-11-14)
We investigated the effects of bioactive-peptides from hydrolysates of flounder fish muscle (FFM) on antioxidant activity. The hydrolysates were prepared by enzymatic reactions of FFM using eight commercial proteases such as papain, pepsin, trypsin, neutrase, alcalase, kojizyme, protamex, and α-chymotrypsin.
Chuan Xiao et al.
European journal of medicinal chemistry, 53, 159-167 (2012-04-24)
A series of 4-methylcoumarin derivatives containing 4,5-dihydropyrazole moiety were synthesized and their antioxidant activities were evaluated in AAPH (2,2'-azobis(2-amidinopropane hydrochloride))-induced oxidation of DNA, and in trapping DPPH (2,2'-diphenyl-1-picrylhydrazyl) and ABTS(+•) (2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical), respectively. Among coumarin derivatives, 3a-d and 4a-c
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