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399655

Sigma-Aldrich

1-Pyrenebutanol

99%

Synonyme(s) :

4-(1-Pyrenyl)butanol, 4-(Pyren-1-yl)butan-1-ol

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About This Item

Formule empirique (notation de Hill):
C20H18O
Numéro CAS:
67000-89-9
Poids moléculaire :
274.36
Numéro MDL:
MFCD00192423
Code UNSPSC :
12352100
ID de substance PubChem :
24864832
Nomenclature NACRES :
NA.22

Pureté

99%

Pf

80-83 °C (lit.)

Chaîne SMILES 

OCCCCc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C20H18O/c21-13-2-1-4-14-7-8-17-10-9-15-5-3-6-16-11-12-18(14)20(17)19(15)16/h3,5-12,21H,1-2,4,13H2

Clé InChI

MRENSFROWALQNU-UHFFFAOYSA-N

Catégories apparentées

Description générale

1-Pyrenebutanol, an alcohol, is an organic building block. It participates in the polymerization of cyclic esters (lactide, δ-valerolactone and ε-caprolactone).

Application

1-Pyrenebutanol may be employed in the following studies:
  • As a new fluorescent substrate to investigate the allosteric mechanism of P450eryF.
  • Preparation of fluorescent polymer based on D,L-lactic acid units end-capped with 1-pyrenebutanol by ring-opening polymerization.
  • Synthesis of 1-pyrenebutanol (PB)-labeled poly(lactic acid) (PLA) nanoparticles (NPs).

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

Certificats d'analyse (COA)

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Cung An Nguyen et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 20(2), 217-222 (2003-10-11)
A new fluorescent polymer based on D,L-lactic acid units end-capped with 1-pyrenebutanol (PLAP) was synthesized by ring-opening polymerization. PLAP having different molecular weight could be obtained by varying the ratio of D,L-lactide and 1-pyrenebutanol. Fluorescent nanoparticles (NP) were prepared using
Dmitri R Davydov et al.
Biochemical and biophysical research communications, 294(4), 806-812 (2002-06-14)
1-Pyrenebutanol (1-PB) has been used as a new fluorescent substrate for P450eryF to explore the molecular mechanisms of cooperativity. Hydroxylation of 1-PB by P450eryF was detected by both fluorometric and chromatographic assays. Binding was monitored by a substrate-induced low-to-high spin
Poly (L-lactide) Nanoparticles via Ring-Opening Polymerization in Non-aqueous Emulsion.
Dorresteijn R, et al.
Macromolecular Chemistry and Physics, 213(19), 1996-2002 (2012)
Kazuki Fukushima et al.
Biomacromolecules, 18(11), 3834-3843 (2017-10-04)
We developed a biodegradable polycarbonate that demonstrates antithrombogenicity and vascular cell adhesion via organocatalytic ring-opening polymerization of a trimethylene carbonate (TMC) analogue bearing a methoxy group. The monoether-tagged polycarbonate demonstrates a platelet adhesion property that is 93 and 89% lower
Dane Christie et al.
ACS central science, 4(4), 504-511 (2018-05-04)
Nanoscale compositional heterogeneity in block copolymers can impart synergistic property combinations, such as stiffness and toughness. However, until now, there has been no experimental method to locally probe the dynamics at a specific location within these structured materials. Here, this
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