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Sigma-Aldrich

Benzenesulfonyl fluoride

99%

Synonyme(s) :

Phenylsulfonyl fluoride

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About This Item

Formule linéaire :
C6H5SO2F
Numéro CAS:
368-43-4
Poids moléculaire :
160.17
Numéro CE :
206-707-2
Numéro MDL:
MFCD00007412
Code UNSPSC :
12352100
ID de substance PubChem :
24857040
Nomenclature NACRES :
NA.22

Pureté

99%

Capacité de réaction

reaction type: click chemistry

Indice de réfraction

n20/D 1.492 (lit.)

Point d'ébullition

207-208 °C (lit.)

Densité

1.333 g/mL at 25 °C (lit.)

Chaîne SMILES 

FS(=O)(=O)c1ccccc1

InChI

1S/C6H5FO2S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H

Clé InChI

IDIPWEYIBKUDNY-UHFFFAOYSA-N

Description générale

The gas-phase fluorine migration reactions of radical cations of benzenesulfonyl fluoride have been studied by electron ionization tandem mass spectrometry.

Application

Benzenesulfonyl fluoride has been used in the preparation of α-sulfonyl phosphonates by direct sulfonylation of lithiated alkyl phosphonates.

Pictogrammes

Skull and crossbonesCorrosion
GHS06,GHS05

Mention d'avertissement

Danger

Mentions de danger

H302 + H312,H314,H331

Classification des risques

Acute Tox. 4 Oral - Skin Corr. 1B

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

188.6 °F - closed cup

Point d'éclair (°C)

87 °C - closed cup

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Jana Maršíková et al.
BMC genomics, 18(1), 814-814 (2017-10-25)
Yeast infections are often connected with formation of biofilms that are extremely difficult to eradicate. An excellent model system for deciphering multifactorial determinants of yeast biofilm development is the colony biofilm, composed of surface ("aerial") and invasive ("root") cells. While
Nehal Narayan et al.
PloS one, 12(10), e0185767-e0185767 (2017-10-03)
The translocator protein (TSPO) is a mitochondrial membrane protein, of as yet uncertain function. Its purported high expression on activated macrophages, has lent utility to TSPO targeted molecular imaging in the form of positron emission tomography (PET), as a means
Lilah Glazer et al.
Journal of proteomics, 128, 333-343 (2015-09-01)
Chitin is a major component of arthropod cuticles, where it forms a three-dimensional network that constitutes the scaffold upon which cuticles form. The chitin fibers that form this network are closely associated with specific structural proteins, while the cuticular matrix
Jun Ren et al.
Aging cell, 16(5), 976-987 (2017-07-07)
Aging is accompanied with unfavorable geometric and functional changes in the heart involving dysregulation of Akt and autophagy. This study examined the impact of Akt2 ablation on life span and cardiac aging as well as the mechanisms involved with a
Ying Gao et al.
Journal of mass spectrometry : JMS, 49(6), 481-489 (2014-06-11)
The gas-phase reactions of Aryl-SF5(·+) and Aryl-SO2F(·+) have been studied with the electron ionization tandem mass spectrometry. Such reactions involve F-atom migration from the S-atom to the aryl group affording the product ion Aryl-F(·+) by subsequent expulsion of SF4 or
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