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206113

Sigma-Aldrich

Platinum(IV) chloride

96%

Synonyme(s) :

Platinum tetrachloride

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About This Item

Formule linéaire :
PtCl4
Numéro CAS:
13454-96-1
Poids moléculaire :
336.89
Numéro CE :
236-645-1
Numéro MDL:
MFCD00011182
Code UNSPSC :
12352302
eCl@ss :
38191307
ID de substance PubChem :
24852378
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

96%

Forme

powder and chunks

Pertinence de la réaction

reagent type: catalyst
core: platinum

Pf

370 °C (dec.) (lit.)

Densité

4.303 g/mL at 25 °C (lit.)

Chaîne SMILES 

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

Clé InChI

FBEIPJNQGITEBL-UHFFFAOYSA-J

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Application

Platinum(IV) chloride can be used as a precursor to synthesize Pt-based nanocatalysts for various organic transformations. For example, Carbon-supported Pt-Ru nanoparticles can be used as an efficient catalyst for methanol and ethanol oxidation.

Due to its high affinity to the glycosyl acceptor hydroxy groups and bidentate ligation capacity, it can be used as a dual catalyst for regio- and stereoselective glycosidation reactions.

It can also be used for the photosensitization and surface modification of TiO2 for the photodegradation of 4-chlorophenol.

Pictogrammes

Skull and crossbonesHealth hazardCorrosion
GHS06,GHS08,GHS05

Mention d'avertissement

Danger

Mentions de danger

H301,H314,H317,H334

Classification des risques

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
MKCQ7860
MKCP7194
MKCM2596
MKCL5692
MKCK6654

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N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
Eric Ennifar et al.
Nucleic acids research, 31(10), 2671-2682 (2003-05-09)
Metal ions, and magnesium in particular, are known to be involved in RNA folding by stabilizing secondary and tertiary structures, and, as cofactors, in RNA enzymatic activity. We have conducted a systematic crystallographic analysis of cation binding to the duplex
B A Teicher et al.
Anticancer research, 13(5A), 1549-1556 (1993-09-01)
Since several anticancer drugs are known to become more cytotoxic to cells in an acidic milieu, we have attempted to utilize the carbonic anhydrase inhibitor, Acetazolamide, to acidify the blood and tumor of C3H mice bearing the FSaIIC fibrosarcoma in
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect
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