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39116

Supelco

Tricyclazole

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

5-Methyl[1,2,4]triazolo[3,4-b][1,3]benzothiazole

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About This Item

Empirical Formula (Hill Notation):
C9H7N3S
CAS Number:
41814-78-2
Molecular Weight:
189.24
Beilstein:
980261
MDL number:
MFCD00072466
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

2-8°C

SMILES string

Cc1cccc2sc3nncn3c12

InChI

1S/C9H7N3S/c1-6-3-2-4-7-8(6)12-5-10-11-9(12)13-7/h2-5H,1H3

InChI key

DQJCHOQLCLEDLL-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified by ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Tricyclazole is a systemic triazolobenzothiazole fungicide used mainly for the control of Pyricularia oryzae on rice. It prevents the fungus from penetrating the epidermis, thereby protecting the plants/and thus, protecting the plants. The compound acts by inhibiting melanization within the appressorium, causing a lack of rigidity in the appressorial wall.

As per Regulation (EC) No 1107/2009, repealing the directive 91/414/EEC, tricyclazole is not approved for use in the European Union. A maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of tricyclazole in fresh/frozen fruits, and tree nuts, in accordance with Regulation (EU) 2017/983.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.

The tricyclazole CRM may also find the following uses:
  • Determination of tricyclazole content in paddy rice using sliver colloid as a substrate and pyridine as an internal standard by surface-enhanced Raman spectroscopy (SERS)
  • To detect residues of tricyclazole and thiram in pear fruit extracts using SERS
  • Dissipation studies of penoxsulam, tricyclazole, and profoxydim in rice paddy systems using HPLC-Diode Array Detection (DAD)
  • Determination of tricyclazole residues in rice using liquid chromatography-tandem mass spectrometry (LC-MS/MS) along with the QuEChERS method of sample preparation
  • Degradation of tricyclazole (TC) in an aqueous solution and real pesticide industry wastewater (RPW) by electron beam (EB) radiation

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301,H412

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 3

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF8981

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Nisar Hussain et al.
Food chemistry, 350, 129025-129025 (2021-02-21)
Silver-coated gold nanoparticles (Au@AgNPs) were optimized with different gold (Au) core sizes and modified surface with mercaptooctane (MCO) to determine fungicide residues in pear fruit extracts. The developed MCO/Au@AgNPs with a gold core size of 28 nm and silver shell thickness
E D Tsochatzis et al.
Chemosphere, 91(7), 1049-1057 (2013-03-20)
Rice cultivation relies on pesticide applications to ensure high yields. However, the regular use of pesticides seriously affects the quality of neighboring surface water systems. Thus complete knowledge of the environmental fate and dissipation of pesticides in the paddy rice

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