901755
nitro-Grela
≥95%
Synonym(s):
(1,3-Dimesitylimidazolidin-2-ylidene)dichloro(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)
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About This Item
Empirical Formula (Hill Notation):
C31H37Cl2N3O3Ru
CAS Number:
Molecular Weight:
671.62
UNSPSC Code:
12161600
NACRES:
NA.22
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Assay
≥95%
form
powder
reaction suitability
core: ruthenium
reagent type: catalyst
mp
>300 °C
storage temp.
2-8°C
Application
nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.
Legal Information
Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222
PCT/EP2003/011222
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Cross-metathesis reaction of vinyl sulfones and sulfoxides.
Grela K, et al.
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A highly efficient ruthenium catalyst for metathesis reactions.
Karol Grela et al.
Angewandte Chemie (International ed. in English), 41(21), 4038-4040 (2002-11-02)
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