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Supelco

Clothianidin-d3

PESTANAL®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-(methyl-d3)-2-nitroguanidine

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About This Item

Empirical Formula (Hill Notation):
C6D3H5ClN5O2S
CAS Number:
1262776-24-8
Molecular Weight:
252.70
MDL number:
MFCD17019117
UNSPSC Code:
41116107
PubChem Substance ID:
329758241
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

Assay

≥97.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

mass shift

M+3

SMILES string

[2H]C([2H])([2H])N\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/i1D3

InChI key

PGOOBECODWQEAB-FIBGUPNXSA-N

Related Categories

General description

Find more information here: Neonicotinoids

Application

Clothianidin-d3 may be used as a standard for the determination of neonicotinoid in milk by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ5146
BCCG1588
BCCD7505
BCBQ6968V
BCBN8335V

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Development and Validation of an Ultra-Sensitive UHPLC-MS/MS Method for Neonicotinoid Analysis in Milk.
Lachat L and Glauser G
Journal of Agricultural and Food Chemistry, 66(32), 8639-8646 (2018)
Daniel B Pickford et al.
Environmental toxicology and chemistry, 37(4), 1040-1050 (2017-11-07)
Thiamethoxam is a widely used neonicotinoid insecticide that has been detected in surface water monitoring programs in North America and Europe. This has led to questions about its toxicity to nontarget insects, specifically those with an aquatic life stage. To
Lucas M Morrison et al.
Journal of AOAC International, 101(6), 1940-1947 (2018-05-23)
Background: Neonicotinoids are among the most widely used insecticides. Recently, there has been concern associated with unintended adverse effects on honeybees and aquatic invertebrates at low parts-per-trillion levels. Objective: There is a need for LC-MS/MS methods that are capable of
Samuel E Baker et al.
Analytical and bioanalytical chemistry, 411(3), 669-678 (2018-11-30)
Neonicotinoid insecticides are widely used replacements for organophosphate and carbamate insecticides, but the extent of human exposure is largely unknown. On the other hand, based on urinary concentrations of DEET metabolites, human exposure to N,N-diethyl-m-toluamide (DEET) appears to be widespread.
Arthur Schaafsma et al.
Environmental toxicology and chemistry, 35(2), 295-302 (2015-09-04)
Neonicotinoid insecticides, especially as seed treatments, have raised concerns about environmental loading and impacts on pollinators, biodiversity, and ecosystems. The authors measured concentrations of neonicotinoid residues in the top 5 cm of soil before planting of maize (corn) in 18 commercial
View All Related Papers

Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Banned and Other Neonicotinoids from Plant Material

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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