932434

TcTa

≥99% (HPLC)

• Synonym(s): 4,4′,4′′-Tri-9-carbazolyltriphenylamine, 4,4′,4′′-tris(carbazol-9-yl)-triphenylamine, 4,4′,4-Tris(carbazol-9-yl)triphenylamine, Tris(4-(9H-carbazol-9-yl)phenyl)amine
• Empirical Formula (Hill Notation): C₅₄H₃₆N₄
• CAS Number: 139092-78-7
• Molecular Weight: 740.89
• MDL number: MFCD03093250
• UNSPSC Code: 41106305
• NACRES: NA.23

Properties

• grade: sublimed grade
• Quality Level: 100
• description: μh ≈ 3.0 x 10^-4 cm² V⁻¹ s⁻¹; μe ≈ 1.0 x 10^-8 cm² V⁻¹ s⁻¹
• Assay: ≥99% (HPLC)
• loss: 0.5% TGA, > 410 °C (weight loss)
• mp: 299 °C
• solubility: THF: soluble; chloroform: soluble; dichloromethane: soluble
• λmax: 293 nm±5 nm in THF; 326 nm±5 nm in THF
• fluorescence: λ_em 385 nm±10 nm in THF
• Orbital energy: HOMO 5.8 eV ; LUMO 2.4 eV
• SMILES string: c1ccc2c(c1)n(-c3ccc(cc3)N(c4ccc(cc4)-n5c6ccccc6c7ccccc57)c8ccc(cc8)-n9c%10ccccc%10c%11ccccc9%11)c%12ccccc2%12
• InChI: 1S/C54H36N4/c1-7-19-49-43(13-1)44-14-2-8-20-50(44)56(49)40-31-25-37(26-32-40)55(38-27-33-41(34-28-38)57-51-21-9-3-15-45(51)46-16-4-10-22-52(46)57)39-29-35-42(36-30-39)58-53-23-11-5-17-47(53)48-18-6-12-24-54(48)58/h1-36H
• InChI key: AWXGSYPUMWKTBR-UHFFFAOYSA-N

Description

Application

It′s a star-shaped carbazole hole-transporting material popularly used in OLEDs as solution-processable fluorescent emitting host, or as electron-blocking layer for quantum-dot light-emitting diodes (QD-LEDs).

TCTA is widely used as a hole transport material in OLED and organic photovoltaic (OPV) devices. It possesses excellent hole injection and transport properties, helping to efficiently transport positive charges (holes) from the anode to the emitting layer.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable