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773506

Sigma-Aldrich

Ethyl 2-(phenylcarbonothioylthio)-2-phenylacetate

98%

Synonym(s):

α-[(Phenylthioxomethyl)thio]benzeneacetic acid ethyl ester, dithiobenzoate RAFT, Benzodithioate phenyl acetic acid ethyl ester

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About This Item

Empirical Formula (Hill Notation):
C17H16O2S2
CAS Number:
1150308-13-6
Molecular Weight:
316.44
MDL number:
MFCD24386381
UNSPSC Code:
12352100
PubChem Substance ID:
329767622
NACRES:
NA.23

Assay

98%

form

solid

mp

48-53 °C

storage temp.

2-8°C

SMILES string

CCOC(=O)C(SC(=S)c1ccccc1)c2ccccc2

InChI

1S/C17H16O2S2/c1-2-19-16(18)15(13-9-5-3-6-10-13)21-17(20)14-11-7-4-8-12-14/h3-12,15H,2H2,1H3

InChI key

SQKNCNYHCGWDEX-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
This is a RAFT agent for controlled radical polymerization, well-suited for methacrylates and methacrylamides. This is a more temperature stable alternative to Aldrich Prod No. 761257. Chain Transfer Agent (CTA)

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN2516

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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