764183

APhos Pd G3

97%

• Synonym(s): APhos-Pd-G3, Palladium G3-(4-(N,N-Dimethylamino)phenyl)di-tert-butylphosphine, [4-(Di-tert-butylphosphino)-N,N-dimethylaniline-2-(2′-aminobiphenyl)]palladium(II) methanesulfonate
• Empirical Formula (Hill Notation): C₂₉H₄₁N₂O₃PPdS
• CAS Number: 1820817-64-8
• Molecular Weight: 635.11
• MDL number: MFCD27978423
• UNSPSC Code: 12161600
• PubChem Substance ID: 329767104
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: solid
• feature: generation 3
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• greener alternative product score: old score: 5; new score: 3; Find out more about DOZN™ Scoring
• greener alternative product characteristics: Waste Prevention; Atom Economy; Less Hazardous Chemical Syntheses; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 192-201 °C (decomposition)
• functional group: phosphine
• greener alternative category: Re-engineered
• SMILES string: NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.CN(C)C3=CC=C(C=C3)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/C16H28NP.C12H10N.CH4O3S.Pd/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI key: SNUBBUQVCDWEAV-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Atom Economy” and “Less Hazardous Chemical Synthesis”. Click here to view its DOZN scorecard.

Application

APhos Pd G3 is a Buchwald precatalyst that can be used in cross-coupling reactions.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable