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Sigma-Aldrich

3,6-Di-tert-butylcarbazole

97%

Synonym(s):

3,6-Di-tert-butyl-9H-carbazole

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About This Item

Empirical Formula (Hill Notation):
C20H25N
CAS Number:
37500-95-1
Molecular Weight:
279.42
MDL number:
MFCD03425849
UNSPSC Code:
12352103
PubChem Substance ID:
329766666
NACRES:
NA.23

Assay

97%

form

powder

mp

228-233

SMILES string

CC(C)(C)c1ccc2[nH]c3ccc(cc3c2c1)C(C)(C)C

InChI

1S/C20H25N/c1-19(2,3)13-7-9-17-15(11-13)16-12-14(20(4,5)6)8-10-18(16)21-17/h7-12,21H,1-6H3

InChI key

OYFFSPILVQLRQA-UHFFFAOYSA-N

Related Categories

General description

3,6-Di-tert-butylcarbazole is a carbazole based material with hole transporting characteristics. The 3,6-Di-tert-butyl component of the carbazole results in an increase in the glass transition temperature (Tg) of the compound. It can be used in combination with another carbazole to form novel electroluminescent materials.

Application

3,6-Di-tert-butylcarbazole is mainly used as a monomeric precursor in the syntheses of new carbazole based materials which consist of ethynylphenyl. These materials include 9-(4-bromophenyl)-3,6-di-tert-butylcarbazol and 2-(4-(2-(4-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)ethynyl)benzylidene)malononitrile (PBM) which can be further be used in organic light emitting diodes (OLEDs) and optical switching devices.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Solvent dependant optical switching in carbazole-based fluorescent nanoparticles.
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Synthesis and photophysical properties of carbazole-based blue light-emitting dendrimers.
Adhikari RM, et al.
The Journal of Organic Chemistry, 72(13), 4727-4732 (2007)
Bis (carbazolyl) derivatives of pyrene and tetrahydropyrene: synthesis, structures, optical properties, electrochemistry, and electroluminescence.
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Journal of Material Chemistry C, 1(8), 1638-1650 (2013)
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Bis(phenylsulfone) was developed as a strong electron acceptor of thermally activated delayed fluorescent emitters. The connection of two electron withdrawing phenylsulfone moieties through meta-position of phenyl produced the bis(phenylsulfone) acceptor and the strong electron acceptor strength of bis(phenylsulfone) enabled preparation
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