713066
1-Butyl-3-methylimidazolium iodide
99%
Synonym(s):
BMIMI
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About This Item
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Assay
≥98.5% (HPLC)
99%
form
liquid
impurities
≤0.5% water
anion traces
bromide (Br-): ≤25 mg/kg
chloride (Cl-): ≤25 mg/kg
fluoride (F-): ≤10 mg/kg
nitrate (NO3-): ≤25 mg/kg
sulfate (SO42-): ≤10 mg/kg
SMILES string
[I-].CCCCn1cc[n+](C)c1
InChI
1S/C8H15N2.HI/c1-3-4-5-10-7-6-9(2)8-10;/h6-8H,3-5H2,1-2H3;1H/q+1;/p-1
InChI key
XREPTGNZZKNFQZ-UHFFFAOYSA-M
General description
1-Butyl-3-methylimidazolium iodide is a room temperature ionic liquid (RTIL).
Application
BMImI can be used as a non-volatile electrolyte in dye-sensitized photochemical cells. It can also be used as a stabilizer/promotor/reaction medium for the transition metal catalyzed biphasic oxidative cyclocarbonylation of β-aminoalcohols and 2-aminophenol to form the corresponding 2-oxazolidinones.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
433.4 °F - closed cup
Flash Point(C)
223 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Theoretical and spectroscopic studies of 1-butyl-3-methylimidazolium iodide room temperature ionic liquid: Its differences with chloride and bromide derivatives.
Journal of Molecular Structure, 975(1), 349-356 (2010)
Pd(Phen)Cl2 stabilized by ionic liquid: an efficient and reusable catalyst for biphasic oxidative cyclocarbonylation of ?-aminoalcohols and 2-aminophenol.
Tetrahedron Letters, 48(28), 4845-4848 (2007)
The journal of physical chemistry. B, 119(28), 8764-8772 (2015-06-20)
Iodide-based ionic liquids have been widely employed as iodide sources in electrolytes for applications utilizing the triiodide/iodide redox couple. While adding a low-viscosity solvent such as water to ionic liquids can greatly enhance their usefulness, mixtures of highly viscous iodide-containing
Development of 151Eu Time-Domain Interferometry and Its Application for the Study of Slow Dynamics in Ionic Liquids
Applied Physics Express, 2.2, 026502-026502 (2009)
Crystal structure of 1-butyl-3-methylimidazolium iodide
Chemistry Letters (Jpn), 35.12, 1400-1401 (2006)
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