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Sigma-Aldrich

F8BT

average Mn ≤25000

Synonym(s):

Poly(9,9-dioctylfluorene-alt-benzothiadiazole), Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]

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About This Item

Linear Formula:
(C35H42N2S)n
CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

mol wt

average Mn ≤25000

solubility

THF: soluble
chloroform: soluble

fluorescence

λex 447 nm; λem 530-560 nm in chloroform

Mw/Mn

<3

semiconductor properties

P-type (mobility=4×10−3 cm2/V·s)

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General description

F8BT is a fluorene copolymer that is used as a light-emitting polymer (LEP) with low energy of lowest unoccupied molecular orbital (LUMO), high electron mobility and luminance.

Application

F8BT can be used with poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PTO) to map the effect of noise sources on photoconducting charge transports by evaluating the conductivity and noise source density (Nt). It may also form a nanocomposite with single walled carbon nanotube (SWCNT) with excellent electric properties and high Seebeck coefficient, for potential application in the development of photovoltaic power and biomass energy. Organic light emitting diode (OLED) devices can be fabricated by depositing a blend of F8 and F8BT on PEDOT:PSS films.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Surface, interface and electronic properties of F8: F8BT polymeric thin films used for organic light-emitting diode applications
Borges BG, et al.
Polymer International, 67(6), 691-699 (2018)
Mapping nanoscale effects of localized noise-source activities on photoconductive charge transports in polymer-blend films
Shekhar S, et al.
Nanotechnology, 29(20), 205204-205204 (2018)
Surface chemistry of photoluminescent F8BT conjugated polymer nanoparticles determines protein corona formation and internalization by phagocytic cells
Ahmad Khanbeigi R, et al.
Biomacromolecules, 16(3), 733-742 (2015)
Morphology-dependent trap formation in bulk heterojunction photodiodes
Shao G, et al.
The Journal of Physical Chemistry B, 117(16), 4654-4660 (2013)
Enhanced figure of merit of poly (9, 9-di-n-octylfluorene-alt-benzothiadiazole) and SWCNT thermoelectric composites by doping with FeCl3
Zhou X, et al.
Journal of Applied Polymer Science, 16(3), 47011-47011 (2018)

Articles

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Materials Design Concepts for Efficient Blue OLEDs: A Joint Theoretical and Experimental Study

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

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