678538
(−)-Ipc2B(allyl)borane solution
1 M in pentane
Synonym(s):
(-)-Ipc2B(allyl) solution, (−)-B-Allyldiisopinocampheylborane solution
About This Item
Recommended Products
optical activity
[α]20/D −35 to ±5°, c = 1
Quality Level
concentration
1 M in pentane
bp
35-36 °C
density
0.638 g/mL at 25 °C
storage temp.
−20°C
SMILES string
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
InChI
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1
InChI key
ZIXZBDJFGUIKJS-RLEROFIGSA-N
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Related Categories
Application
Other Notes
accessory
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-56.2 °F - closed cup
Flash Point(C)
-49 °C - closed cup
Personal Protective Equipment
Certificates of Analysis (COA)
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Articles
Asymmetric allylboration of aldehydes is an extremely important method for preparation of homoallylic alcohols, as evidenced in numerous complex natural product syntheses.
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