667811
(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane
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About This Item
Empirical Formula (Hill Notation):
C34H36P2
CAS Number:
Molecular Weight:
506.60
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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form
solid
Quality Level
mp
143-147 °C
SMILES string
C1C[C@@H](P(CCP2[C@H](CC[C@@H]2c3ccccc3)c4ccccc4)[C@H]1c5ccccc5)c6ccccc6
InChI
1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m1/s1
InChI key
VHHAZLMVLLIMHT-YFRBGRBWSA-N
Application
(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane can be used:
- As a chiral ligand in the 1,3-dipolar cycloaddition reaction of azomethyne yielded [70]fullerene enantiomers; catalyzed by silver.
- As a component of the catalytic system along with silver, which is used for the synthesis of fullerene hybrids.
Legal Information
Sold in collaboration with Namena Corp. for research purposes only.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Hierarchical Selectivity in Fullerenes: Site-, Regio-, Diastereo-, and Enantiocontrol of the 1, 3-Dipolar Cycloaddition to C70
Maroto EE, et al.
Angewandte Chemie (International Edition in English), 50(27), 6060-6064 (2011)
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