567159

1,1′-Bis(phenylphosphinidene)ferrocene

97%

• Synonym(s): 1,1′-(Ferrocenediyl)phenylphosphine
• Linear Formula: C₅H₄PC₆H₅C₅H₄Fe
• CAS Number: 72954-06-4
• Molecular Weight: 292.09
• MDL number: MFCD04974069
• UNSPSC Code: 12352005
• PubChem Substance ID: 24880349
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 88-92 °C (lit.)
• functional group: phosphine
• storage temp.: 2-8°C
• SMILES string: [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
• InChI: 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
• InChI key: HKOUDNXXOXEYNZ-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves