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482293

Sigma-Aldrich

Tetraammineplatinum(II) nitrate

99.995% trace metals basis

Synonym(s):

Platinum tetraamine dinitrate, Tetraamineplatinum(II) dinitrate, Tetraamminedinitratoplatinum

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About This Item

Linear Formula:
[Pt(NH3)4](NO3)2
CAS Number:
20634-12-2
Molecular Weight:
387.21
EC Number:
243-929-9
MDL number:
MFCD00011624
UNSPSC Code:
12161600
PubChem Substance ID:
24871708
NACRES:
NA.22

Assay

99.995% trace metals basis

form

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

262 °C (dec.) (lit.)

SMILES string

N.N.N.N.[Pt++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pt/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

RBAKORNXYLGSJB-UHFFFAOYSA-N

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Application

Tetraammineplatinum(II) nitrate can be used as a platinum (Pt) precursor to synthesize platinum-based catalysts such as Pt/cerium oxide catalysts and Pt/mesoporous carbon catalysts. It is also used in synthesizing lean NOx trap (LNT) catalysts.

Pictograms

Exploding Bomb
GHS01

Signal Word

Danger

Hazard Statements

H240,H412

Hazard Classifications

Aquatic Chronic 3 - Org. Perox. A

Supplementary Hazards

EUH044

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ9057
MKCQ6560
MKCP3106
MKCN7121
MKCN4794

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High performance monolithic catalysts for hydrogenation reactions.
Perez-Cadenas A F, et al.
Catalysis Today, 105(3-4), 623-628 (2005)
NOx storage and reduction properties of model ceria-based lean NOx trap catalysts.
Shi C, et al.
Applied Catalysis. B, Environmental, 119, 183-196 (2012)
Preparation of Pt/mesoporous carbon (MC) electrode catalyst and its reactivity toward oxygen reduction.
Hayashi A, et al.
Electrochimica Acta, 53(21), 6117-6125 (2008)
Ghorban Ali Moghani et al.
Journal of Zhejiang University. Science. B, 6(3), 222-226 (2005-02-01)
Let G be a weighted graph with adjacency matrix A=[a(ij)]. An Euclidean graph associated with a molecule is defined by a weighted graph with adjacency matrix D=[d(ij)], where for i not = j, d(ij) is the Euclidean distance between the
Austin B Yongye et al.
Journal of computer-aided molecular design, 24(3), 225-235 (2010-03-25)
The potential energy surfaces of chiral tetraamine Pt(II) coordination complexes were computed at the B3LYP/LANL2DZ level of theory by a systematic variation of two dihedral angles: C12-C15-C34-C37 (theta) and C24-C17-C31-C48 (psi) employing a grid resolution of 30 degrees . Potential
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