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About This Item
Empirical Formula (Hill Notation):
C9H7NO · xH2O
CAS Number:
Molecular Weight:
145.16 (anhydrous basis)
Beilstein:
5989589
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
mp
52-55 °C (lit.)
SMILES string
[H]O[H].[O-][n+]1cccc2ccccc12
InChI
1S/C9H7NO.H2O/c11-10-7-3-5-8-4-1-2-6-9(8)10;/h1-7H;1H2
InChI key
CUSWDTBBCIXCRB-UHFFFAOYSA-N
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General description
Quinoline N-oxide hydrate forms complexes with lanthanide chloride.
Application
Quinoline N-oxide hydrate was used in quantitative determination of nitrones using trifluoroacetic anhydride-sodium iodide reagent.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Lanthanide chloride complexes with quinoline-n-oxide.
Kingston JV, et al.
J. Inorg. Nucl. Chem., 31(10), 3181-3185 (1969)
The application of trifluoroacetic anhydride-sodium iodide (TFAA-I) system for quantitative determination of nitrones.
Clesielski W, et al.
Canadian Journal of Chemistry, 68(5), 679-684 (1990)
Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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