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113379

Sigma-Aldrich

Chloro(dimethyl)phenylsilane

98%

Synonym(s):

DMPSCl, Dimethylphenylchlorosilane, Dimethylphenylsilylchloride, Phenyldimethylchlorosilane

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About This Item

Linear Formula:
C6H5Si(CH3)2Cl
CAS Number:
768-33-2
Molecular Weight:
170.71
Beilstein:
606292
EC Number:
212-193-0
MDL number:
MFCD00000499
UNSPSC Code:
12352002
PubChem Substance ID:
24846878

Quality Level

100

Assay

98%

refractive index

n20/D 1.509 (lit.)

density

1.017 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(Cl)c1ccccc1

InChI

1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

KWYZNESIGBQHJK-UHFFFAOYSA-N

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Application

Used in a synthesis of enantioenriched allenylsilanes via an ortho-ester Claisen rearrangement of chiral, silylpropargylic alcohols.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

143.6 °F - closed cup

Flash Point(C)

62 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Carlton P Folster et al.
Dalton transactions (Cambridge, England : 2003), 49(45), 16125-16132 (2020-01-30)
The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended
Ryan A Brawn et al.
Organic letters, 9(14), 2689-2692 (2007-06-15)
A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used as carbon nucleophiles in three-component, Lewis acid mediated additions to in situ generated oxonium ions
M Okamoto
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 112(6), 409-413 (1992-06-01)
The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosilane in xylene, were studied by high-performance liquid chromatography using carbamazepine and diphenylhydantoin as model compounds. From the elemental

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