101346
Dichlorophenylborane
97%
Synonym(s):
NSC 93889, Phenylboron dichloride, Phenyldichloroborane
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About This Item
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Assay
97%
reaction suitability
reagent type: reductant
refractive index
n20/D 1.545 (lit.)
bp
66 °C/11 mmHg (lit.)
density
1.224 g/mL at 25 °C (lit.)
SMILES string
ClB(Cl)c1ccccc1
InChI
1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H
InChI key
NCQDQONETMHUMY-UHFFFAOYSA-N
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Application
Catalyst for:
- Antiproliferative macrolide and cell migration inhibitor lactimidomycin
- Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
- Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
- Stereoselective alkylative ring opening of cyclic anhydrides
- Cross-metathesis reaction of amino derivatives with olefins
- Asymmetric acetate aldol reactions
- The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
Dichlorophenylborane can be used as a catalyst for:
- The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin.
- Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions.
- Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives.
- Stereoselective alkylative ring opening of cyclic anhydrides.
- Cross-metathesis reaction of amino derivatives with olefins.
- Asymmetric acetate aldol reactions.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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