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Merck

Protecting-group-free total synthesis of (+/-)-subincanadine F.

The Journal of organic chemistry (2009-09-26)
Pinhong Chen, Lidong Cao, Chaozhong Li
RESUMO

With chemoselective Dieckmann condensation as the key step, the protective-group-free total synthesis of (+/-)-subincanadine F was accomplished in 7 steps from the commercially available tryptamine in 33% overall yield.

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Methyl bromopyruvate, technical