901062

Pinacol (dichloromethyl) boronate

≥95%

• Sinônimo(s): 1,3,2-Dioxaborolane, 2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Dichloromethyl pinacol boronate
• Fórmula empírica (Notação de Hill): C₇H₁₃BCl₂O₂
• Número CAS: 83622-41-7
• Peso molecular: 210.89
• Número MDL: MFCD27976342
• Código UNSPSC: 12352200
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥95%
• forma: (Powder or Solid or Crystals or Semi-Solid or Liquid)
• índice de refração: n/D 1.4511
• densidade: 1.1423
• grupo funcional: chloro
• InChI: 1S/C7H13BCl2O2/c1-6(2)7(3,4)12-8(11-6)5(9)10/h5H,1-4H3
• chave InChI: GQFQFYFLABSDDS-UHFFFAOYSA-N

Descrição

Aplicação

Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity.

Outras notas

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 201.2 °F
• Ponto de fulgor (°C): 94 °C