254312

Titanium(IV) chloride

≥99.995% trace metals basis

• Synonym(s): TTC, Titanium tetrachloride
• Linear Formula: TiCl₄
• CAS Number: 7550-45-0
• Molecular Weight: 189.68
• EC Number: 231-441-9
• MDL number: MFCD00011267
• UNSPSC Code: 12352300
• PubChem Substance ID: 329752736
• NACRES: NA.55
• Assay: ≥99.995% trace metals basis
• form: liquid; liquid

Properties

• vapor pressure: 50 mmHg ( 55 °C); 9.6 mmHg ( 20 °C)
• Quality Level: 100
• Assay: ≥99.995% trace metals basis
• form: liquid; liquid
• reaction suitability: reagent type: catalyst; core: titanium
• bp: 135-136 °C (lit.); 136.4 °C
• mp: −25 °C (lit.)
• density: 1.73 g/mL at 20 °C (lit.)
• SMILES string: Cl[Ti](Cl)(Cl)Cl
• InChI: 1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
• InChI key: XJDNKRIXUMDJCW-UHFFFAOYSA-J

Description

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl₄ having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Promotes a highly selective aldol reaction of (S)-2-benzyloxy-3-pentanone in THF or DME.

Titanium(IV) chloride has been used in the synthesis of anatase TiO₂ structures with macropores (250nm in diameter) and mesoscale pores (50nm in diameter).

Safety Information

• Pictograms: GHS06,GHS05
• Signal Word: Danger
• Hazard Statements: H314,H330,H335
• Precautionary Statements: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014
• Storage Class Code: 6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable