911402

(CyPAd-DalPhos)NiCl(otol)

≥95%

• Synonym(s): 8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
• Empirical Formula (Hill Notation): C₃₅H₄₉ClNiO₃P₂
• CAS Number: 2115838-60-1
• Molecular Weight: 673.86
• UNSPSC Code: 12352200
• NACRES: NA.22

Properties

• Assay: ≥95%
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• mp: 193-197 °C

Description

Application

(CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp²)-O coupling and N-arylation reactions.

Other Notes

Technology Spotlight: DalPhos ligands

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Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

Safety Information

• Pictograms: GHS08,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H302 + H312 + H332,H341,H351,H372,H410
• Precautionary Statements: P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation
• Target Organs: Respiratory Tract,Skin
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable