77292
Pentafluoropropionic anhydride
purum, ≥97.0% (GC)
Synonym(s):
PFPA, Perfluoropropionic anhydride
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About This Item
Linear Formula:
(CF3CF2CO)2O
CAS Number:
Molecular Weight:
310.05
Beilstein:
1806446
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
purum
Quality Level
Assay
≥97.0% (GC)
form
liquid
bp
69-70 °C/735 mmHg (lit.)
density
1.571 g/mL at 25 °C (lit.)
functional group
anhydride
ester
fluoro
SMILES string
FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F
InChI
1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
InChI key
XETRHNFRKCNWAJ-UHFFFAOYSA-N
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Application
PFPA acylates amines, amino acids and other compounds. PFPA derivatives are highly volatile; used in GC separation
Pentafluoropropionic anhydride can be used to synthesize lithium 4,5-dicyano-2-(pentafluoroethyl)imidazole, a novel imidazole-derived salt with potential application as an electrolyte in lithium-ion batteries. It can also be used to prepare 1.3- bis(pentafluoropropionyl)azulene.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Chemical Derivatization in Gas Chromatography.
J. Drozd et al.
J. Chromatogr. Library, 19 (1981)
New type of imidazole based salts designed specifically for lithium ion batteries.
Niedzicki L, et al.
Electrochimica Acta, 55(4), 1450-1454 (2010)
Simple syntheses of 1, 3-bis (perfluoroacyl) azulenes and 1, 3-azulenedicarboxylic acid.
Mathias L J and Overberger C G
The Journal of Organic Chemistry, 45(9), 1701-1703 (1980)
D.R. Knapp
Handbook of Analytical Derivatization Reactions (1979)
J. Drozd
J. Chromatogr. Library, 19 (1981)
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