682691

Bis(tri-tert-butylphosphine)platinum(0)

• Synonym(s): Bis[tris(1,1-dimethylethyl)phosphine]platinum
• Linear Formula: [((CH₃)₃C)₃P]₂Pt
• CAS Number: 60648-70-6
• Molecular Weight: 599.71
• MDL number: MFCD04974248
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760505
• NACRES: NA.22

Properties

• form: solid
• reaction suitability: core: platinum; reagent type: catalyst
• mp: 260-269 °C
• storage temp.: 2-8°C
• SMILES string: [Pt].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/2C12H27P.Pt/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
• InChI key: RJQWVEJVXWLMRE-UHFFFAOYSA-N

Description

Application

Reactant for synthesis of:

• Trimetallic ReBiPt complexes
• Rhodium-germanium carbonyl complexes

Catalyst for the synthesis of:

• Amidobipyridyl inhibitors of protein kinase D
• 5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling

Catalyst for phenyl and methyl group transfer from tin to iridium

Activator of metal hydride complexes

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable