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450103

Sigma-Aldrich

Yttrium(III) chloride

AnhydroBeads, −10 mesh, 99.99% trace metals basis

Synonym(s):

Yttrium trichloride

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About This Item

Linear Formula:
YCl3
CAS Number:
Molecular Weight:
195.26
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

product line

AnhydroBeads

Quality Level

Assay

99.99% trace metals basis

impurities

≤150.0 ppm Trace Rare Earth Analysis

particle size

−10 mesh

mp

721 °C (lit.)

density

2.67 g/mL at 25 °C (lit.)

SMILES string

Cl[Y](Cl)Cl

InChI

1S/3ClH.Y/h3*1H;/q;;;+3/p-3

InChI key

PCMOZDDGXKIOLL-UHFFFAOYSA-K

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Application

Used to prepare yttrium alkyl alkoxide complexes under strictly anhydrous conditions.

Features and Benefits

Will react with potassium alkoxotitanates to form precursors to novel titanium-containing ceramics

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1B

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Evans, W.J. et al.
Organometallics, 15, 1351-1351 (1996)
K Marubashi et al.
Toxicology letters, 99(1), 43-51 (1998-11-04)
We investigated pulmonary clearance of yttrium (Y) and acute lung injury following intratracheal instillation (i.t.) of yttrium chloride (YCl3) in saline- or YCl3-pretreated rats (30 days before the second challenge). About 67% of the initial dose of Y remained in
N Watanabe et al.
Radiation protection dosimetry, 114(4), 509-513 (2005-05-19)
The efficacy of diethylenetriaminepentaacetate calcium trisodium (CaNa(3)DTPA) in a dose of 34.7 micromol kg(-1) as a function of its route of administration was investigated in rats with a puncture wound contaminated by (90)Y-chloride at a concentration of 2.55 MBq kg(-1).
Jérôme Hannedouche et al.
Chemical communications (Cambridge, England), (30)(30), 3552-3554 (2008-07-26)
A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl(3) or YCl(3)(THF)(3.5) with ligand (R)- and n-BuLi is described.
Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi.
Naoki Hirone et al.
Angewandte Chemie (International ed. in English), 49(42), 7762-7764 (2010-09-08)

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