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449679

Sigma-Aldrich

Barium isopropoxide

powder, 99% trace metals basis

Synonym(s):

Barium diisopropoxide, Barium isopropoxide, Diisopropoxybarium

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About This Item

Linear Formula:
Ba(OCH(CH3)2)2
CAS Number:
24363-37-9
Molecular Weight:
255.50
MDL number:
MFCD00050486
UNSPSC Code:
12352103
PubChem Substance ID:
24868500
NACRES:
NA.23

Assay

99% trace metals basis

form

powder
solid

reaction suitability

core: barium

mp

200 °C (dec.) (lit.)

SMILES string

CC(C)O[Ba]OC(C)C

InChI

1S/2C3H7O.Ba/c2*1-3(2)4;/h2*3H,1-2H3;/q2*-1;+2

InChI key

CPUJSIVIXCTVEI-UHFFFAOYSA-N

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Application

For preparation of bimetallic Ba-Nb and Ba-Zr alkoxides. Asymmetric aldol reactions are promoted by a novel catalyst prepared from Ba(O-i-Pr)2.
It may be used as a catalyst for one pot preparation of symmetrical 1,5-diketones. Sol gel synthesis of ternary compound, Ba3 Li 2Ti8 O20 can be carried out by precursor reactants, barium isopropoxide, titanium isopropoxide and lithium acetate.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H252,H302 + H332

Hazard Classifications

Acute Tox. 4 Oral - Self-heat. 2

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Yamada, Y.M.A. Shibasaki, M.
Tetrahedron Letters, 39, 5561-5561 (1998)
Turevskaya, E.P. et al.
Polyhedron, 14, 1531-1531 (1995)
Preparation of YBaCuO powder by sol-gel techniques using molecular precursors.
El Khokh N, et al.
Journal of Materials Science Letters, 8.7, 762-764 (1989)
One-pot synthesis of 1,5-diketones catalyzed by barium isopropoxide
Yanagisawa A, et al.
Tetrahedron, 63.35, 8581-8585 (2007)

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