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Assay
97%
form
powder and chunks
SMILES string
[Li+].CC(C)(C)[O-]
InChI
1S/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
LZWQNOHZMQIFBX-UHFFFAOYSA-N
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Application
Other synthetic applications:
- In combination with potassium diisopropylamide, LiOtBu can be used to deprotonate 1-(phenylseleno) alkenes and bis (phenylseleno) acetals.
- LiOtBu can mediate the α-alkylation reaction of ketones with primary alcohols in the absence of any transition metal catalyst.
- LiOtBu is an effective base for the synthesis of 3,4,5-trisubstituted 3H-oxazol-2-ones and 3,4-disubstituted (Z)-oxazolidin-2-ones from substituted propargyl alcohols and aryl/alkyl isocyanates using DMF as a solvent.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Self-heat. 1 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Personal Protective Equipment
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