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333557

Sigma-Aldrich

(1-Bromovinyl)trimethylsilane

97%

Synonym(s):

α-(Trimethylsilyl)vinyl bromide

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About This Item

Linear Formula:
H2C=C(Br)Si(CH3)3
CAS Number:
Molecular Weight:
179.13
Beilstein:
1742258
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

>1 (vs air)

Quality Level

Assay

97%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

124 °C/745 mmHg (lit.)

density

1.156 g/mL at 25 °C (lit.)

functional group

bromo

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C(Br)=C

InChI

1S/C5H11BrSi/c1-5(6)7(2,3)4/h1H2,2-4H3

InChI key

VVDJVCJVVHHCIB-UHFFFAOYSA-N

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General description

Tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reactions of (1-bromovinyl)trimethylsilane with organozinc bromides were studied.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

55.4 °F - closed cup

Flash Point(C)

13 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Abnormal products of palladium catalysed coupling reactions of (1-bromovinyl) trimethylsilane.
Ennis DS and Gilchrist TL.
Tetrahedron Letters, 30(28), 3735-3736 (1989)

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