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233544

Sigma-Aldrich

4-Dodecylaniline

97%

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About This Item

Linear Formula:
CH3(CH2)11C6H4NH2
CAS Number:
104-42-7
Molecular Weight:
261.45
Beilstein:
2646305
EC Number:
203-201-3
MDL number:
MFCD00007919
UNSPSC Code:
12352100
PubChem Substance ID:
24853981
NACRES:
NA.22

Assay

97%

form

solid

bp

220-221 °C/15 mmHg (lit.)

mp

35-39 °C (lit.)

SMILES string

CCCCCCCCCCCCc1ccc(N)cc1

InChI

1S/C18H31N/c1-2-3-4-5-6-7-8-9-10-11-12-17-13-15-18(19)16-14-17/h13-16H,2-12,19H2,1H3

InChI key

KLPPPIIIEMUEGP-UHFFFAOYSA-N

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Application

4-Dodecylaniline has been used:
  • in the synthesis of sodium 4-dodecylphenylazosulfonate
  • to investigate the water solubilization of single-walled carbon nanotubes (SWNTs)
  • in proton transfer step during molecular oxygen (O2) reduction by decamethylferrocene (DMFc)

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H400

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

302.0 °F - closed cup

Flash Point(C)

150 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ1864
MKBT7433V
MKBK2935V
MKBG4457V
MKBF7764

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A photodestructible surfactant.
Dunkin IR, et al.
Journal of the Chemical Society. Chemical Communications, 19, 2245-2246 (1994)
Su B, et al.
Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline.
Journal of Electroanalytical Chemistry, 639(1), 102-108 (2010)
Water solubilization of single-walled carbon nanotubes by functionalization with glucosamine.
Pompeo F and Resasco DE.
Nano Letters, 2(4), 369-373 (2002)
Kyle A Brown et al.
Nature methods, 16(5), 417-420 (2019-04-17)
We report the identification of a photocleavable anionic surfactant, 4-hexylphenylazosulfonate (Azo), which can be rapidly degraded by ultraviolet irradiation, for top-down proteomics. Azo can effectively solubilize proteins with performance comparable to that of sodium dodecyl sulfate (SDS) and is compatible

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